LABORATORY ORGANIC REACTIONS OF MICROPOROUS MATERIALS

RESEARCH INTERESTS

Main research topics:
• Synthesis of micro/mesoporous and nanostructured oxides.

• Development of methods for functionalization with different organic groups of nanosized mesoporous silica materials with different morphology.

• Modification of mesoporous materials with nanosized transition metal/ metal oxide species.

• Physicochemical characterization of modified materials (temperature gravimetrical analysis, temperature programmed reduction, infrared spectroscopy, UV-VIS spectroscopy, adsorption methods etc.).

• Investigation of catalytic properties of modified nanocomposite materials:

- Methanol conversion to hydrocarbons, hydrogen, CO and methane as a source of alternative ecological fuel from renewable sources and industry supply with gas mixtures;
- Catalytic combustion of different volatile organic compounds (VOCs) for environmental protection;
- Conversion of alkylaromatic hydrocarbons for petrochemical industry;
- Selective oxidation of alcohols and olefins in gas or in liquid phase for the preparation of intermediates for pharmacy and chemical industry.

• Investigation of the relation between catalyst composition, structure and catalytic behaviour. Genesis of the catalytic sites and mechanism of the catalytic processes.

• Preparation of new drug delivery systems on the basis of mesoporous silicas with different structure, morphology, particle size and surface functionality.

• Study on the optimization of the loading capacity and release properties of loaded drugs - antibiotics, glucocorticoids, anti-inflammatory non-steriods and antioxidants.

Laboratory members

Head:

Prof. DSc. Margarita Popova


(+359 2) 960 6111
411
Margarita.Popova@orgchm.bas.bg
Name Room Phone Å-mail*
Prof. Margarita Popova, DSc, Head 411 111 Margarita.Popova
Assoc. Prof. Momtchil Dimitrov, PhD 410 111 Momchil.Dimitrov
Assoc. Prof. Gloria Issa, PhD 402 109 Gloria.Issa
Assist. Prof. Consolato Rosmini, PhD 402 109 Consolato.Rosmini
Ivalina Trendafilova, PhD 411 110 Ivalina.Trendafilova
Assist. Manuela Oykova 411 111 Manuela.Oykova
Assist. Oyundari Tumurbaatar 515 Oyundari.Tumurbaatar
Assist. Ivan Dimitrov 410 111 Ivan.Dimitrov
Assist. Gregoria Theochari 411 111 Gregoria.Theochari
Stela Grozdanova, chemist 411 111 Stela.Grozdanova
Associated members
Prof. Tanya Hristova, DSc 409 979 6640 Tanya.Tsoncheva

Projects

Financing organization: Recovery and Resilience Plan, BG-RRP-2.015-0002 - Strengthening research potential by attracting and retaining talented researchers (2024) Project title: "Aqueous Phase Reforming of bio-waste polyols for simultaneous green hydrogen and fine chemicals production (X-ASPERA)" Period of implementation: From November 2024 to May 2026 Coordinator of the research team: Assistant Professor Consolato Rosmini, PhD

Selected publications

2024

Applied Catalysis B: Environment and Energy,350,
123904
Unveiling the synergistic effects of pH and Sn content for tuning the catalytic performance of Ni0/NixSny intermetallic compounds dispersed on Ce-Zr mixed oxides in the aqueous phase reforming of ethylene glycol

2022

Carbon,196,
186-202
Mesoporous Ce–Fe–Ni nanocomposites encapsulated in carbon-nanofibers: Synthesis, characterization and catalytic behavior in oxygen evolution reaction

2021

ACS Appl. Mater. Interfaces,13, 1,,
1838–1852
Formation of Catalytic Active Sites in Hydrothermally Obtained Binary Ceria–Iron Oxides: Composition and Preparation Effects

2018

Microporous and Mesoporous Materials,
263, 28-33
Nanostructured silver silica materials as potential propolis carriers
Applied Catalysis A: General, 560,
119-131
Efficient solid acid catalysts based on sulfated tin oxides for liquid phase esterification of levulinic acid with ethanol.
Microporous and Mesoporous Materials,
263, 96-105
Novel SO3H functionalized magnetic nanoporous silica/polymer nanocomposite as a carrier in a dual-drug delivery system for anticancer therapy
Microporous and Mesoporous Materials,
270, 40-47
Amino-modified KIT-6 mesoporous silica/polymer composites for quercetin delivery: Experimental and theoretical approaches
Microporous and Mesoporous Materials,
259, 9-16
Activated carbons from used motor oil as catalyst support for sustainable environmental protection
Biomass and
Bioenergy,
109, 135-146
Activated carbon from Bulgarian peach stones as a support of catalysts for methanol decomposition